Who married Louis Marie Joseph de Brigode?

Louis Marie Joseph de Brigode (21 October 1776, Lille - 22 September 1827, Bourbonne-les-Bains) was a French politician under the First French Empire and the Bourbon Restoration. He was from an old noble family from French Flanders and his elder brother Romain-Joseph de Brigode-Kemlandt was also a nobleman and politician. He is also notable as the first husband of Émilie Pellapra.

Émilie Louise Marie Françoise Joséphine Pellapra (11 November 1806 – 22 May 1871), comtesse de Brigode, princesse de Chimay, was the daughter of Françoise-Marie LeRoy and possibly Napoleon I of France. She claimed to be the product of her mother's affair with the French Emperor which supposedly took place in April 1805, but this date is impossible with Émilie's birth in November 1806. She was first married to Count Louis-Marie of Brigode and later married to Prince Joseph de Riquet de Caraman, 17th prince de Chimay.