Who married Charles, Duke of Guise?

Charles de Lorraine, 4th Duke of Guise and 3rd Prince of Joinville (20 August 1571 – 30 September 1640), was the son of Henry I, Duke of Guise and Catherine of Cleves, and succeeded his father as Duke of Guise in 1588. Initially part of the Catholic league, he pledged his support for Henry IV of France and was made Admiral of the Levant by Louis XIII. After siding with the Queen Mother, Marie de' Medici, against Cardinal Richelieu, he fled to Italy with his family where he died in 1640.

Henriette Catherine de Joyeuse (8 January 1585 – 25 February 1656) was the daughter of Henri de Joyeuse and Catherine de Nogaret de La Valette. She married her first husband, Henri de Bourbon, Duke of Montpensier, on 15 May 1597 and her second husband, Charles, Duke of Guise, on 6 January 1611.